The 5 volt spec used 2 x 220 ohms. The 3.3 volt spec uses 10 & 33
That seems proportionally incorrect.
The voltage drop over the receiver (1.1 V over the 220 Ω resistor, and somewhere between 1.1 V and 1.7 V over the optocoupler's LED) should stay constant. The transmitter's resistors must drop the remaining voltage; in the worst case, this would be about
5.0 V − 1.1 V − 1.7 V = 2.2 V, or
3.3 V − 1.1 V − 1.7 V = 0.5 V.
(The section "Low-Voltage Signaling Technical Notes" of CA33 shows how to compute the resistor values. However, in practice, designers make less pessimistic assumptions about the LED forward voltage; many 3.3 V devices actually use 2× 47 Ω in the transmitter.)